Showing posts with label Chitosan. Show all posts
Showing posts with label Chitosan. Show all posts

Sunday, February 19, 2012

What is Chitosan

Chitosan is by nature widespread presence of chitin (chitin) after deacetylation, the chemical name the polydextrose amine (1-4) -2 - amino-BD glucose, since 1859, the Frenchman Rouget first to get chitosan, bio-functional nature of this natural polymer, excellent performance and compatibility, blood compatibility, security, microbial degradability was all walks of life widespread concern in the pharmaceutical, food, chemical, cosmetics, water treatment and metal recovery and recycling, biochemical and biomedical engineering in many fields of applied research has made significant progress. For patients, chitosan, lowering blood pressure, blood sugar lowering effect has been reported.
Chitosan is a product of chitin N-deacetylation, In general, an N-acetyl take off more than 55 percent can be called chitosan, or, in 1% acetic acid or 1% hydrochloric acid dissolving 1% of the deacetylation of chitin, the deacetylation of chitin is called chitosan. "Alias ​​chitosan, the deacetylation of chitin deacetylation of chitin, soluble chitin, soluble chitin, Chitosan and chitosan", "crustaceans sugar, The glycosaminoglycan crustaceans polysaccharides, chitosan polysaccharide "chemical called beta-(1 → 4) -2 - amino - 2 - deoxy-D-glucose, the structure shown in Figure. The degree of deacetylation (DD), determines the macromolecular chains of amino (NH2) content, and DD increase in amine protonated leaving charged groups of chitosan in dilute acid solution increased, the polyelectrolyte charge density increase, Xanthan Gum the result will inevitably lead to changes in its structure, properties and performance, since the nature of the chitosan in dilute solution studies have ignored the DD value equation. VANDUM, who studied the influence of ionic strength on the molecular size and viscosity of chitosan in dilute aqueous solution. Concluded that the ionic strength will change the degree of swelling of the random coil, thus changing the molecular size and intrinsic viscosity, the MARK the-HOUWINK equation constants of different DD chitosan results show that the K A value with changes in DD values . By MARK-HOUWINK equation constants K, A regular depends on the chitosan deacetylation degree, but at the same molecular weight, with the increase of degree of deacetylation of chitosan in dilute solutions of molecular size, intrinsic viscosity degree, and the expansion factor increases, the characteristic ratio and food additives steric factors decrease with the increase of the degree of deacetylation. Thus within the scope of any one chitosan samples through relatively simple intrinsic viscosity measurements, to calculate the average molecular weight, which could accumulate the basic data for further research.

Chitosan apearance and molecular weight

Pure chitin and chitosan is a white or gray translucent flake or powder solid, tasteless, odorless, non-toxic, pure chitosan slightly pearly luster. Organisms chitin relative molecular mass of 1 × 106 × 106, were extracted chitin relative molecular mass of about 3 × 105 × 105, taken by the chitin system chitosan relative molecular mass of more low, about 2 × 105 ~ 5 × 105. Chitin and chitosan relative molecular mass of the size of the manufacturing process, generally the value of the viscosity level of Goods chitosan depending on the different uses three different viscosity, high viscosity product is 0.7 ~ 1Pa · s in viscosity product is 0.25 ~ 0.65 Pa · s, low viscosity product <0.25 Pa · s. Manufacture of fiber products must be used to the high viscosity of chitin or chitosan.
Chemical properties
Under certain conditions, chitosan can occur hydrolysis, alkylation, acylation, carboxylation, methylation, sulfonation, nitration, halogenation, oxidation, reduction, condensation and complexation chemical reaction, can generate a variety of different properties of chitosan derivatives, thereby expanding the scope of application of chitosan.
Chitosan macromolecule lively hydroxyl food additives and amino groups, which have a strong chemical reaction capability. C-6 hydroxyl can occur under alkaline conditions the following reaction: hydroxyethyl - chitosan with ethylene oxide reaction, available hydroxyethyl derivatives. Carboxymethylation - chitosan with chloroacetic acid reaction will have to carboxymethylation of derivatives. Sulfonic acid esterification - chitin and chitosan and cellulose treated with alkali to generate sulfonic acid ester reaction with carbon disulfide. Cyanoethylated - acrylonitrile and chitosan addition reaction to generate the cyanoethylated derivatives. Chitin and chitosan, the above reaction in the introduction of large side groups, destruction of its crystalline structure, and thus improve the solubility, water-soluble carboxymethyl derivatives show the nature of the polyelectrolyte in solution.

Sunday, October 9, 2011

Chitosan CAS No is 9012-76-4

Chitosan is produced commercially by deacetylation of chitin, which is the structural element in the exoskeleton of crustaceans.A common method for the synthesis of chitosan is the deacetylation of chitin using sodium hydroxide in excess as a reagent and water as a solvent.
Chitosan and its derivatives, such as trimethylchitosan,have been used in nonviral gene delivery.In agriculture, chitosan is used primarily as a natural seed treatment and plant growth enhancer, and as an ecologically friendly biopesticide substance that boosts the innate ability of plants to defend themselves against fungal infections.It is one of the most abundant biodegradable materials in the world. Degraded molecules of chitin/chitosan exist in soil and water.
Chitosan CAS No is 9012-76-4 increases photosynthesis, promotes and enhances plant growth, stimulates nutrient uptake, increases germination and sprouting, and boosts plant vigor. When used as seed treatment or seed coating on cotton, corn, seed potatoes, soybeans, sugar beets, tomatoes, wheat and many other seeds, it elicits an innate immunity response in developing roots which destroys parasitic cyst nematodes without harming beneficial nematodes and organisms.Chitosan has a rich history of being researched for applications in agriculture and horticulture dating back to the 1980s.
Chitosan applications to protect plants have been used in space, as well. Chitosan can as a food additives. NASA first flew a chitosan experiment to protect adzuki beans grown aboard the space shuttle and Mir space station in 1997. Chitosan can also be used in water processing engineering as a part of a filtration process. Chitosan causes the fine sediment particles to bind together, and is subsequently removed with the sediment during sand filtration.

Others: L-Carnitine Tartrate          L-Carnitine hydrochloride